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This relative resistance likely reflects preferential preservation of mtGSH, which accounts for only ~1015% of total cellular GSH but constitutes the principal antioxidant defense within mitochondria

Current Opinion in Food Science , 34 , 2129

Pineal gland regulation: The tetrapeptide modulates melatonin synthesis in the pineal gland, potentially restoring age-related declines in melatonin production that contribute to disrupted circadian rhythms and reduced antioxidant defense

In fact, a study found between 50 and 70 percent of women will develop melasma, dark patches known as the the mask of pregnancy. You might also notice darkened skin on other areas of the body such the areolas or the linea nigra, a line extending over the centre of the belly